The regular expression I receive the most feedback, not to mention "bug" reports on, is the one you'll find right on this site's home page: \b[A-Z0-9._%+-]+@[A-Z0-9.-]+\.[A-Z]{2,4}\b. This regular expression, I claim, matches any email address. Most of the feedback I get refutes that claim by showing one email address that this regex doesn't match. Usually, the "bug" report also includes a suggestion to make the regex "perfect".
As I explain below, my claim only holds true when one accepts my definition of what a valid email address really is, and what it's not. If you want to use a different definition, you'll have to adapt the regex. Matching a valid email address is a perfect example showing that (1) before writing a regex, you have to know exactly what you're trying to match, and what not; and (2) there's often a trade-off between what's exact, and what's practical.
The virtue of my regular expression above is that it matches 99% of the email addresses in use today. All the email address it matches can be handled by 99% of all email software out there. If you're looking for a quick solution, you only need to read the next paragraph. If you want to know all the trade-offs and get plenty of alternatives to choose from, read on.
If you want to use the regular expression above, there's two things you need to understand. First, long regexes make it difficult to nicely format paragraphs. So I didn't include a-z in any of the three character classes. This regex is intended to be used with your regex engine's "case insensitive" option turned on. (You'd be surprised how many "bug" reports I get about that.) Second, the above regex is delimited with word boundaries, which makes it suitable for extracting email addresses from files or larger blocks of text. If you want to check whether the user typed in a valid email address, replace the word boundaries with start-of-string and end-of-string anchors, like this:^[A-Z0-9._%+-]+@[A-Z0-9.-]+\.[A-Z]{2,4}$.
The previous paragraph also applies to all following examples. You may need to change word boundaries into start/end-of-string anchors, or vice versa. And you will need to turn on the case insensitive matching option.